If a molecule can hydrogen bond does it guarantee that it will have a higher boiling point than a molecule that cannot?

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11-11-2017
Chemistry

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If a molecule can hydrogen bond does it guarantee that it will have a higher boiling point than a molecule that cannot?

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ahmedishaal ahmedishaal · Answer 1 · 2017-11-22T23:25:09+01:00

A molecule that can h-bond will not always necessarily and does not have guarantee to have a higher boiling point than one than cannot have h-bond.
we can take an example of Pentan-2-one that cannot h-bond but instead of this it has a high boiling point that is 102.3 °C, while propan-1-ol can h-bond but it has a boiling point of 97.2°C, that is lower than the boiling point of Pentan-2-one.